Experimental procedures for the synthesis of all compounds 1–15 and their characterization data; optimization experiments for the synthesis of compounds 2, 4, 5, 7, 8, 10, and 11; copies of 1H NMR and 13C NMR spectra for new compounds 2–6, 8, and 10–15; crystal structure determination data of cages R-14 and S-16 (PDF)