Feasibility of Metallurgical Waste Encapsulation in a Clay Formed Matrix
IOP Conference Series: Material Science and Engineering 2011
Inna Juhņeviča, Jekaterina Kučinska, Aļona Sardiko, Gundars Mežinskis

As a result of Joint Stock Company "Liepajas Metalurgs" production process there are produced certain quantity of substances that are harmful for environment and have to be encapsulated into stable structures. Company's target is modification of these substances into products that form stable compounds in order to avoid metal release in environment. Geopolymers can be synthesized from many materials with a high concentration of aluminosilicates such as metakaolin or fly ash. Heavy metal immobilization in geopolymeric structures is not thought to be caused by physical encapsulation alone, but also through adsorption of the metal ions into the geopolymer structure and possibly even bonding of the metal ions into the structure. All samples have been analyzed with X-Ray, FTIR spectroscopy; chemical analysis and compressive strength tests have been performed. Chemical analysis of geopolymeric samples shows that the main component leached from samples during the boiling in water is Na2O that can be explained by more alkaline components nature – Na2SiO3, NaOH, and SO3. Fe2O3 and ZnO are not detected in water extracts at all samples. As a result of Joint Stock Company "Liepajas Metalurgs" production process there are produced certain quantity of substances that are harmful for environment and have to be encapsulated into stable structures. Company's target is modification of these substances into products that form stable compounds in order to avoid metal release in environment. Geopolymers can be synthesized from many materials with a high concentration of aluminosilicates such as metakaolin or fly ash. Heavy metal immobilization in geopolymeric structures is not thought to be caused by physical encapsulation alone, but also through adsorption of the metal ions into the geopolymer structure and possibly even bonding of the metal ions into the structure. All samples have been analyzed with X-Ray, FTIR spectroscopy; chemical analysis and compressive strength tests have been performed. Chemical analysis of geopolymeric samples shows that the main component leached from samples during the boiling in water is Na2O that can be explained by more alkaline components nature – Na2SiO3, NaOH, and SO3. Fe2O3 and ZnO are not detected in water extracts at all samples. As a result of Joint Stock Company "Liepajas Metalurgs" production process there are produced certain quantity of substances that are harmful for environment and have to be encapsulated into stable structures. Company's target is modification of these substances into products that form stable compounds in order to avoid metal release in environment. Geopolymers can be synthesized from many materials with a high concentration of aluminosilicates such as metakaolin or fly ash. Heavy metal immobilization in geopolymeric structures is not thought to be caused by physical encapsulation alone, but also through adsorption of the metal ions into the geopolymer structure and possibly even bonding of the metal ions into the structure. All samples have been analyzed with X-Ray, FTIR spectroscopy; chemical analysis and compressive strength tests have been performed. Chemical analysis of geopolymeric samples shows that the main component leached from samples during the boiling in water is Na2O that can be explained by more alkaline components nature – Na2SiO3, NaOH, and SO3. Fe2O3 and ZnO are not detected in water extracts at all samples. As a result of Joint Stock Company „Liepajas Metalurgs” production process there are produced certain quantity of substances that are harmful for environment and have to be encapsulated into stable structures. Company’s target is modification of these substances into products that form stable compounds in order to avoid metal release in environment. Geopolymers can be synthesized from many materials with a high concentration of aluminosilicates such as metakaolin or fly ash. Heavy metal immobilization in geopolymeric structures is not thought to be caused by physical encapsulation alone, but also through adsorption of the metal ions into the geopolymer structure and possibly even bonding of the metal ions into the structure. All samples have been analyzed with X-Ray, FTIR spectroscopy; chemical analysis and compressive strength tests have been performed. Chemical analysis of geopolymeric samples shows that the main component leached from samples during the boiling in water is Na2O that can be explained by more alkaline components nature – Na2SiO3, NaOH, and SO3. Fe2O3 and ZnO are not detected in water extracts at all samples


Keywords
Ceramic materials, industrial waste
DOI
10.1088/1757-899X/25/1/012007
Hyperlink
http://iopscience.iop.org/1757-899X/25/1/012007

Juhņeviča, I., Kučinska, J., Sardiko, A., Mežinskis, G. Feasibility of Metallurgical Waste Encapsulation in a Clay Formed Matrix. IOP Conference Series: Material Science and Engineering, 2011, Vol.25, Iss.1, pp.012007-012007. ISSN 1757-8981. e-ISSN 1757-899X. Available from: doi:10.1088/1757-899X/25/1/012007

Publication language
English (en)
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