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Publikācija: An Improved Molecular Design of Obtaining NLO Active Molecular Glasses Using Triphenyl Moieties as Amorphous Phase Formation Enhancers

Publication Type Scientific article indexed in SCOPUS or WOS database
Funding for basic activity Unknown
Defending: ,
Publication language English (en)
Title in original language An Improved Molecular Design of Obtaining NLO Active Molecular Glasses Using Triphenyl Moieties as Amorphous Phase Formation Enhancers
Field of research 1. Natural sciences
Sub-field of research 1.4 Chemical sciences
Authors Kaspars Traskovskis
Igors Mihailovs
Andrejs Tokmakovs
Valdis Kokars
Mārtiņš Rutkis
Keywords NLO, azochromophore, molecular glasses
Abstract New molecular design of obtaining molecular glasses has been developed by linking triphenylmethyl moieties to chromophore core by flexible C-C bridge. Compounds capable of forming stable amorphous phase with good optical quality have been acquired with increased chemical and thermal sustainability compared to the previously reported design. NLO activity of compounds has been measured after corona discharge polling. Compared to previously synthesized trityloxy fragment containing compounds increase of d33 coefficient by up to 17 times was achieved for the same chromophore core containing compounds.
DOI: 10.1117/12.922391
Hyperlink: http://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=1316429 
Reference Traskovskis, K., Mihailovs, I., Tokmakovs, A., Kokars, V., Rutkis, M. An Improved Molecular Design of Obtaining NLO Active Molecular Glasses Using Triphenyl Moieties as Amorphous Phase Formation Enhancers. Proceedings of SPIE, 2012, Vol.8434: Nonlinear Optics and Applications VI, pp.1-8. ISSN 0277-786X. e-ISSN 1996-756X. Available from: doi:10.1117/12.922391
Additional information Citation count:
ID 13321