One of the main tasks of presented research are to impact the additional value on natural fabrics by adding them new properties with a metal nano-level coating, evaluate coating technologies. Having the ability to control the surface of a natural fiber offers great rewards that go far beyond pure economics as natural fibers are renewable and biodegradable. The paper describes the process of vacuum evaporation and magnetron sputtering of copper coatings on cotton textile materials, analysis of the metal coated textile surface by laser laboratory complex and SEM. The investigation results evince that laser laboratory complex measurements of reflected and through covered material transmitted light can be applied to trace the unevenness of deposited metal film on the covered fabric surface and its changes from exploitation impacts without samples destruction.