Crystal Structure of 3-amino-5,5-dimethyl-2-[(E)-2-nitroethenyl]cyclohex-2-en-1-one
Acta Crystallographica Section E: Structure Reports Online
2014
Brigita Vīgante,
Dmitrijs Stepanovs,
Andrejs Pelšs,
Anatolijs Mišņovs
The asymmetric unit of the title compound, C10H14N2O3, contains two independent molecules with similar conformations. In the both molecules, the cyclohexene rings adopt the same envelope conformation with the flap C atoms lying 0.658 (3) and 0.668 (3) Å from the mean planes formed by the remaining atoms. In the crystal, adjacent molecules are connected via N-H...O hydrogen bonds and weak C-H...O interactions, forming supramolecular layers parallel to (-101).
Keywords
Nitrodienamines; nitroacetaldehyde; Knoevenagel-type condensation; crystal structure; hydrogen bonds.
DOI
10.1107/S1600536814023009
Hyperlink
http://journals.iucr.org/e/issues/2014/11/00/xu5825/index.html
Vīgante, B., Stepanovs, D., Pelšs, A., Mišņovs, A. Crystal Structure of 3-amino-5,5-dimethyl-2-[(E)-2-nitroethenyl]cyclohex-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 2014, Vol.70, Part 11, pp.379-381. e-ISSN 1600-5368. Available from: doi:10.1107/S1600536814023009
Publication language
English (en)