Copper-Catalyzed Intermolecular C—H Amination of (Hetero)arenes via Transient Unsymmetrical λ3-Iodanes

ChemInform 2014
Igors Sokolovs, Dmitrijs Lubriks, Edgars Sūna

A one-pot two-step method for intermolecular C–H amination of electron-rich heteroarenes and arenes has been developed. The approach is based on a room-temperature copper-catalyzed regioselective reaction of the in situ formed unsymmetrical (hetero)aryl-λ3-iodanes with a wide range of primary and secondary aliphatic amines and anilines.

Keywords
Copper-Catalyzed Intermolecular C—H Amination (Hetero)arenes Transient Unsymmetrical λ3-Iodanes
DOI
10.1002/chin.201448037
Hyperlink
http://onlinelibrary.wiley.com/doi/10.1002/chin.201448037/abstract

Sokolovs, I., Lubriks, D., Sūna, E. Copper-Catalyzed Intermolecular C—H Amination of (Hetero)arenes via Transient Unsymmetrical λ3-Iodanes. ChemInform, 2014, Vol.45, Iss.48, pp.37-37. ISSN 1522-2667. Available from: doi:10.1002/chin.201448037

Publication language
English (en)