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Publikācija: Application of Element Organic Compound-Derived Allylsulfinates in Organic Synthesis

Publication Type Conference paper
Funding for basic activity Unknown
Defending: ,
Publication language English (en)
Title in original language Application of Element Organic Compound-Derived Allylsulfinates in Organic Synthesis
Field of research 1. Natural sciences
Sub-field of research 1.4 Chemical sciences
Authors Agnese Stikute
Vilnis Peipiņš
Mikus Puriņš
Māris Turks
Keywords Allylsilanes, Allylboranes, allylsilylsulfinates, sulfur dioxide
Abstract We have developed a novel approach to sulfoxide synthesis which is based on sila-ene reaction between allylsilanes and SO2 followed by LiCl- or ZnCl2-assisted Grignard reagent addition to the S-center of silyl sulfinate. The scope of the method has been demonstrated with the successful use of aryl-, alkyl, allyl- and heterocyclic Grignard reagents.
Hyperlink: http://www.boschem.eu/public/BOS2016/BOS-2016_Anstract-Book_Final.pdf 
Reference Stikute, A., Peipiņš, V., Puriņš, M., Turks, M. Application of Element Organic Compound-Derived Allylsulfinates in Organic Synthesis. In: Balticum Organicum Syntheticum: Program and Abstracts, Latvia, Rīga, 3-6 July, 2016. Rīga: 2016, pp.153-153.
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ID 22714