Titanium dioxide is very promising material for photocatalysts, decomposition of organic compounds, splitting of water, for manufacturing self-cleaning materials and dyesensitized solar cells. It is generally concluded that the photocatalytic activity depends on the specific surface area, phase composition and presence of dopants, which promotes absorption of visible light. Doped with sulfur nanotubes and nanopores were prepared by their treatment at 380o C in H2S flow or by using method of micro arc oxidation in sulfur containing electrolyte. The catalytic activity was determined by degradation of MB solution under UV and visible light illumination. The prepared photocatalysts have higher activity with respect to pure TiO2 nanotubes.