N,N-Diethylanilinium Complex with Borodicitric Acid: Synthesis and Crystal Structure

Russian Journal of Inorganic Chemistry 2017
Irēna Zviedre, Sergejs Beļakovs

N,N-diethylanilinium bis(citrato)borate [C6H5NH(C2H5)2][(C6H6O7)2B] (I) has been synthesized for the first time. Single crystals were obtained; the crystal structure was studied by X-ray crystallography. Crystals of I are triclinic, space group P-1, a = 9.6183(2) Å, b = 10.3153(3) Å, c = 13.7364(4) Å,  = 69.0304(12),  = 77.0394(13),  = 89.5518(10), V = 1236.25(6) Å3, Z = 2, calc = 1.454 g/cm3. The structural units of compound I are large complex bis(citrato)borate anions with spiran structure and N,N-diethylanilinium cations. Hydrogen bond system is formed by five independent contacts of O–H...O, O–H...O, OI and N–H...O types.

Keywords
Boron coordination compounds, bis(citrato)borate, X-ray analysis
DOI
10.1134/S0036023617050254
Hyperlink
https://link.springer.com/article/10.1134%2FS0036023617050254

Zviedre, I., Beļakovs, S. N,N-Diethylanilinium Complex with Borodicitric Acid: Synthesis and Crystal Structure. Russian Journal of Inorganic Chemistry, 2017, Vol.62, No.5, pp.665-670. ISSN 0036-0236. e-ISSN 1531-8613. Available from: doi:10.1134/S0036023617050254

Publication language
English (en)