Close-Spaced Sublimation of SnS Absorber Layers and SnS/CdS Heterojunction Solar Cells with Mo and Ti Back Metal Contacts
Thin Solid Films 2020
Andrii Voznyi, Volodymyr Kosyak, Yurii Yeromenko, Jan Keller, Astrīda Bērziņa, Artem Shamardin, Igor Iatsunskyi, Igor Shpetnyi, Sergei Plotnikov, Anatoliy Opanasyuk

Tin sulfide is a promising semiconductor candidate to replace the currently used absorber materials in thin film photovoltaic such as Cu(In,Ga)(S,Se)2 and CdTe devices, which use toxic and scarce elements. However, numerous challenges still remain to approach comparable efficiencies for SnS-based solar cells. In this report, we address the following: (i) impact of growth conditions on phase purity and crystal quality of SnS thin films deposited by close-spaced vacuum sublimation technique; (ii) based on optimized SnS growth conditions, we further fabricate tin sulfide solar cells using traditional CdS buffer and i-ZnO/ZnO:Al bilayers and investigate the impact of molybdenum and titanium back metal contacts on photovoltaic parameters of resulting devices; (iii) finally, using device simulations, we reveal the impact of minority carrier lifetime in the SnS absorber and recombination velocity at the SnS/CdS heterointerface on solar cell parameters, demonstrating that these are the main factors affecting the performance of SnS-based photovoltaic devices.


Keywords
Tin sulfide Thin films, Close-spaced sublimation Solar cells Device simulation
DOI
10.1016/j.tsf.2020.138153
Hyperlink
https://www.sciencedirect.com/science/article/pii/S0040609020303631

Voznyi, A., Kosyak, V., Yeromenko, Y., Keller, J., Bērziņa, A., Shamardin, A., Iatsunskyi, I., Shpetnyi, I., Plotnikov, S., Opanasyuk, A. Close-Spaced Sublimation of SnS Absorber Layers and SnS/CdS Heterojunction Solar Cells with Mo and Ti Back Metal Contacts. Thin Solid Films, 2020, Vol. 709, Article number 138153. ISSN 0040-6090. Available from: doi:10.1016/j.tsf.2020.138153

Publication language
English (en)
The Scientific Library of the Riga Technical University.
E-mail: uzzinas@rtu.lv; Phone: +371 28399196