C-H Bond Functionalization by High-Valent Cobalt Catalysis: Current Progress, Challenges and Future Perspectives
Chemical Communications 2021
Lūkass Tomass Lukašēvics, A Cizikovs, Liene Grigorjeva

Over the last decade, high-valent cobalt catalysis has earned a place in the spotlight as a valuable tool for C-H activation and functionalization. Since the discovery of its unique reactivity, more and more attention has been directed towards the utilization of cobalt as an alternative to noble metal catalysts. In particular, Cp*Co(iii) complexes, as well as simple Co(ii) and Co(iii) salts in combination with bidentate chelation assistance, have been extensively used for the development of novel transformations. In this review, we have demonstrated the existing trends in the C-H functionalization methodology using high-valent cobalt catalysis and highlighted the main challenges to overcome, as well as perspective directions, which need to be further developed in the future.


Keywords
Catalysis; Cobalt; Gateways (computer networks); Manganese compounds; Silver compounds
DOI
10.1039/d1cc04382j
Hyperlink
https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC04382J

Lukašēvics, L., Cizikovs, A., Grigorjeva, L. C-H Bond Functionalization by High-Valent Cobalt Catalysis: Current Progress, Challenges and Future Perspectives. Chemical Communications, 2021, Vol. 57, No. 83, pp.10827-10841. ISSN 1359-7345. e-ISSN 1364-548X. Available from: doi:10.1039/d1cc04382j

Publication language
English (en)
The Scientific Library of the Riga Technical University.
E-mail: uzzinas@rtu.lv; Phone: +371 28399196