Rupe Rearrangement Studies in Liquid Sulfur Dioxide

Materials Science and Applied Chemistry II: Selected, peer reviewed papers from the 59th International Scientific Conference of Riga Technical University (RTU), Section of Materials Science and Applied Chemistry - MSAC 2018. Key Engineering Materials. Vol.800 2019
Kristaps Leškovskis, Jevgeņija Lugiņina, Krista Gulbe, Māris Turks

Copper(II) and indium(III) triflate catalyzes the Rupe rearrangement of propargylic alcohols in liquid sulfur dioxide as the reaction medium. 1-Ethynylcyclohexanol and 1- (phenylethynyl)cyclohexan-1-ol were used as model substrates, and the expected 1-(cyclohex-1-en1-yl)ethanone and 1-(cyclohex-1-en-1-yl)-2-phenylethanone were obtained in average yields.

Keywords
Rupe rearrangement liquid sulfur dioxide
DOI
10.4028/www.scientific.net/KEM.800.42
Hyperlink
https://www.scientific.net/KEM.800.42

Leškovskis, K., Lugiņina, J., Gulbe, K., Turks, M. Rupe Rearrangement Studies in Liquid Sulfur Dioxide. In: Materials Science and Applied Chemistry II: Selected, peer reviewed papers from the 59th International Scientific Conference of Riga Technical University (RTU), Section of Materials Science and Applied Chemistry - MSAC 2018. Key Engineering Materials. Vol.800, Latvia, Riga, 26-26 October, 2018. Switzerland: Trans Tech Publications, 2019, pp.42-46. ISBN 978-3-0357-1407-4. e-ISBN 978-3-0357-3407-2. ISSN 1013-9826. e-ISSN 1662-9795. Available from: doi:10.4028/www.scientific.net/KEM.800.42

Publication language
English (en)