Synthesis and Crystal Structure of the Complex N,N-Dimethylanilinium Dicitratoborate Monohydrate = Синтез и кисталлическая структура комплекса N,N-диметиланилиния с бородилимонной кислотой
Russian Journal of Inorganic Chemistry (Engl. Transl.)
2012
Irēna Zviedre,
Sergejs Beļakovs
N,N-Dimethylanilinium dicitratoborate monohydrate [C6H5NH(CH3)2][(C6H6O7)2B]·H2O (I) was synthesized for the first time. Single crystals were obtained in an aqueous solution; the crystal structure was studied by X-ray crystallography. Crystals of I are triclinic, space group P1 ¯ , a = 9.7017(2) Å, b = 11.0475(2) Å, c = 12.6282(2) Å, α = 106.595(2)°, β = 106.931(1)°, Γ = 103.568(1)°, V = 1163.97(4) Å3, Z = 2, ρcalc = 1.516 g/cm3. The structural units of compound 1 are large complex dicitratoborate anions with a spiran structure, N,N-dimethylanilinium cations, and crystal water molecules. The crystal packing is a three-dimensional framework. A hydrogen-bond system is formed by seven independent contacts O(N)-H…O.
DOI
10.1134/S0036023612060290
Zviedre, I., Beļakovs, S. Synthesis and Crystal Structure of the Complex N,N-Dimethylanilinium Dicitratoborate Monohydrate = Синтез и кисталлическая структура комплекса N,N-диметиланилиния с бородилимонной кислотой. Russian Journal of Inorganic Chemistry (Engl. Transl.), 2012, Vol. 57, No. 10, 1348.-1354.lpp. ISSN 0036-0236. e-ISSN 1531-8613. Pieejams: doi:10.1134/S0036023612060290
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