Crystal Structure of 3-amino-5,5-dimethyl-2-[(E)-2-nitro­ethen­yl]cyclo­hex-2-en-1-one

Acta Crystallographica Section E: Structure Reports Online 2014
Brigita Vīgante, Dmitrijs Stepanovs, Andrejs Pelšs, Anatolijs Mišņovs

The asymmetric unit of the title compound, C10H14N2O3, contains two independent mol­ecules with similar conformations. In the both mol­ecules, the cyclo­hexene rings adopt the same envelope conformation with the flap C atoms lying 0.658 (3) and 0.668 (3) Å from the mean planes formed by the remaining atoms. In the crystal, adjacent mol­ecules are connected via N-H...O hydrogen bonds and weak C-H...O inter­actions, forming supra­molecular layers parallel to (-101).

Atslēgas vārdi
Nitro­dienamines; nitro­acetaldehyde; Knoevenagel-type condensation; crystal structure; hydrogen bonds.
DOI
10.1107/S1600536814023009
Hipersaite
http://journals.iucr.org/e/issues/2014/11/00/xu5825/index.html

Vīgante, B., Stepanovs, D., Pelšs, A., Mišņovs, A. Crystal Structure of 3-amino-5,5-dimethyl-2-[(E)-2-nitro­ethen­yl]cyclo­hex-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 2014, Vol.70, Part 11, 379.-381.lpp. e-ISSN 1600-5368. Pieejams: doi:10.1107/S1600536814023009

Publikācijas valoda
English (en)