Study of the Li3Fe1.2Sc0.75Y0.05(PO4)3 Ceramics by Impedance and Mössbauer Spectroscopy
Solid State Ionics 2017
T. Šalkus, E. Kazakevičius, J. Reklaitis, V. Venckute, S. Daugela, R. Davidonis, D. Baltrunas, Dagnija Valdniece, Antonija Dindune, A.F. Orliukas

Li3Fe1.2Sc0.75Y0.05(PO4)3 compound has been synthesized by solid state reaction method. The results of X-ray diffraction (XRD) investigation have shown that synthesized powders belong to monoclinic symmetry (space group P21/n) with Z = 4 formula units in the unit cell. For the study of electrical properties ceramic samples were prepared. For measurements of electrical impedance in the frequency range 10 Hz – 1 MHz two and four probe methods were used. Coaxial line was used for the investigation of impedance spectra in the frequency range from 1 MHz to 3 GHz. The electrical properties of the ceramics were studied in the temperature interval from room temperature (RT) to 600 K. The Mössbauer spectra were measured in the temperature interval (10 – 600) K.


Atslēgas vārdi
ionic conductivity; Phase transition; Mössbauer spectroscopy
DOI
10.1016/j.ssi.2016.12.027
Hipersaite
http://www.sciencedirect.com/science/article/pii/S0167273816304970

Šalkus, T., Kazakevičius, E., Reklaitis, J., Venckute, V., Daugela, S., Davidonis, R., Baltrunas, D., Valdniece, D., Dindune, A., Orliukas, A. Study of the Li3Fe1.2Sc0.75Y0.05(PO4)3 Ceramics by Impedance and Mössbauer Spectroscopy. Solid State Ionics, 2017, Vol.302, 30.-34.lpp. ISSN 0167-2738. Pieejams: doi:10.1016/j.ssi.2016.12.027

Publikācijas valoda
English (en)
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