Crystal Chemical Peculiarities of the N,N-Diethylanilinium Bis(citrato)borate [C6H5NH(C2H5)2][(C6H6O7)2B]

Riga Technical University 57th International Scientific Conference "Materials Science and Applied Chemistry" (MSAC 2016): Proceedings and Programme 2016
Irēna Zviedre, Sergejs Beļakovs

N,N-diethylanilinium bis(citrato)borate [C6H5NH(C2H5)2][(C6H6O7)2B] (I) has been synthesized for the first time. Single crystals were obtained; the crystal structure was studied by X-ray crystallography. Crystals of I are triclinic, space group P-1, a = 9.6183(2) Å, b = 10.3153(3) Å, c = 13.7364(4) Å,  = 69.0304(12),  = 77.0394(13),  = 89.5518(10), V = 1236.25(6) Å3, Z = 2, calc = 1.454 g/cm3. The structural units of compound I are large complex bis(citrato)borate anions with spiran structure and N,N-diethylanilinium cations. Hydrogen bond system is formed by five independent contacts of O–H...O, O–H...O, OI and N–H...O types.

Atslēgas vārdi
Boron coordination compounds, bis(citrato)borates, synthesis of monocrystals, X-ray diffraction analysis
Hipersaite
https://conferences.rtu.lv/index.php/MSAC/MSAC2016/paper/viewFile/11/2

Zviedre, I., Beļakovs, S. Crystal Chemical Peculiarities of the N,N-Diethylanilinium Bis(citrato)borate [C6H5NH(C2H5)2][(C6H6O7)2B]. No: Riga Technical University 57th International Scientific Conference "Materials Science and Applied Chemistry" (MSAC 2016): Proceedings and Programme, Latvija, Riga, 21.-21. oktobris, 2016. Riga: RTU Press, 2016, 207.-210.lpp. ISBN 978-9934-10-861-7.

Publikācijas valoda
English (en)