The process of Ag+ ions extraction from nitric solutions by bulk liquid membranes containing di(2-ethylhexyl) phosphoric acid and tri-n-octylamine accompanied with silver(I) electrodeposition from perchloric acid solutions is studied at galvanostatic electrodialysis. The effects of the current density as well as of composition of the liquid membrane and aqueous solutions on the rate of the silver(I) transport are determined. More than 90% of silver ions was extracted from the feed solution containing 0.01 mol l1 AgNO3 and about 40% of metal was electrodeposited during 1 h of electrodialysis. Sound adherent silver coatings have been deposited on platinum and copper cathodes.