Renewable Hydrocarbon Production via Rapeseed Oil Hydrotreatment over Palladium Catalysts
IOP Conference Series: Earth and Environmental Science. Vol.897: 4th International Conference on Renewable Energy and Environment Engineering 2021
Ilze Māliņa, Kristaps Māliņš, Mihails Strods Vavilovs, Veniamins Uleiskis

The effect of SiO2-Al2O3 (Pd5%/SA), activated carbon (Pd5%/C) and Al2O3 (Pd5%/A) supported palladium (5%) catalysts on renewable hydrocarbon synthesis via rapeseed oil hydrotreatment was investigated. The hydrotreatment experiments were carried out in solvent free medium under initial H2 pressure 100 bar and at 340 C temperature for 120 min using catalyst amount 5%. Gas chromatography-mass spectrometry (GC/MS) analysis were used for estimation of hydrocarbon content in the obtained samples. Pd5%/SA catalyst provided complete conversion of rapeseed oil into marketable liquid renewable hydrocarbons without presence of oxygen containing substances under studied hydrotreatment conditions. Moreover, all tested Pd catalysts gave narrow range of linear saturated hydrocarbons (n-C15-C19). Pd5%/C and Pd5%/A catalysts gave partial feedstock conversion into hydrocarbons even in long residence time. Overall liquid hydrocarbon yields were from 55.3% to 82.3%.


Atslēgas vārdi
Hydrotreatment, Pd catalysts, renewable hydrocarbons
DOI
10.1088/1755-1315/897/1/012012
Hipersaite
https://iopscience.iop.org/article/10.1088/1755-1315/897/1/012012/meta#artAbst

Māliņa, I., Māliņš, K., Strods Vavilovs, M., Uleiskis, V. Renewable Hydrocarbon Production via Rapeseed Oil Hydrotreatment over Palladium Catalysts. IOP Conference Series: Earth and Environmental Science, 2021, Vol. 897, Article number 012012. ISSN 1755-1307. Pieejams: doi:10.1088/1755-1315/897/1/012012

Publikācijas valoda
English (en)
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