Mitigating CO2 emissions has become a top question in international and national arenas, likewise on the city level. To initiate and maintain transformative policies related to climate neutrality, an evident-based multi-sectoral forecasting model needs to be timely and effectively deployed. Decarbonisation solutions should be considered from the economic, environmental, and social perspectives. The resulting complexity constitutes an essential barrier to implementing CO2 valorisation projects. This study aims to analyse barriers and driving factors for the sustainable development of CO2 valorisation options. In order to reach the research goal, a methodological approach based on the combination of strengths, weaknesses, opportunities, and threats analysis, Geographical Information System and Fuzzy Logic Cognitive Analysis method was used. The method has been applied to a case study in Latvia