Hollow core fibers, supporting waveguiding in a void, open a room of opportunities for numerous applications owing to an extended light-matter interaction distance and relatively high optical confinement. Decorating an inner capillary with functional materials allows tailoring the fiber's optical properties further and turns the structure into a functional device. Here, we functionalize an anti-resonant hollow-core fiber with 18 nm-size gold nanoparticles, approaching a uniform 45% surface coverage along 10 s of centimeters along its inner capillary. Owing to a moderately low overlap between the fundamental mode and the gold layer, the fiber maintains its high transmission properties; nevertheless, the entire structure experiences considerable heating, which is observed and quantified with the aid of a thermal camera. The hollow core and the surrounding capillary are subsequently filled with ethanol and thermo-optical heating is demonstrated. We also show that at moderate laser intensities, the liquid inside the fiber begins to boil and, as a result, the optical guiding is destroyed. The gilded hollow core fiber and its high thermal-optical responsivity suggest considering the structure as an efficient optically driven catalytic reactor in applications where either small reaction volumes or remote control over a process are demanded.