Synthesis and Physical Properties of Polyazido Purine and Homopurine
Balticum Organicum Syntheticum 2024: Book of Abstracts 2024
Kristaps Valkovskis, Irina Novosjolova, Māris Turks

Binary CxNy organic compounds are impact-sensitive and possess explosive properties due to the high nitrogen content. The performance of nitrogen-rich compounds is attributed to the high heat of formation. Moreover, the main combustion product of such nitrogen-rich compounds is non toxic nitrogen gas rather than the CO2 from oxidation of a carbon backbone. Hence, nitrogen-rich compounds are currently the most promising candidates for the next-generation “green” explosives. To the best of our knowledge, purine and its homologue - pyrimido[5,4-d]pyrimidine have not been used in the synthesis of energetic materials before. However, the nitrogen-rich backbone presents excellent features for application as high energy density materials. Recently, we have designed an approach towards binary C6N16 compound and triazidopurine and tested their energetic properties.


Keywords
Pirimidīns, azīds, tetrazols
Hyperlink
https://boschem.eu/bos2024/wp-content/uploads/sites/5/2024/07/BOS2024_Abstract-Book.pdf

Valkovskis, K., Novosjolova, I., Turks, M. Synthesis and Physical Properties of Polyazido Purine and Homopurine. In: Balticum Organicum Syntheticum 2024: Book of Abstracts, Latvia, Rīga, 7-10 July, 2024. Riga: 2024, pp.111-111.

Publication language
English (en)
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