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Publikācija: Novel Synthesis of 2-Trichloromethyl-4-Vinyloxazoline and Its Derivatization by Ring Cleavage Reactions

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Publikācijas valoda English (en)
Nosaukums oriģinālvalodā Novel Synthesis of 2-Trichloromethyl-4-Vinyloxazoline and Its Derivatization by Ring Cleavage Reactions
Pētniecības nozare 1. Dabaszinātnes
Pētniecības apakšnozare 1.4. Ķīmija
Autori Liene Grigorjeva
Ansis Maļeckis
Kristīne Kļimoviča
Marija Skvorcova
Natalija Ivdra
Gundars Leitis
Aigars Jirgensons
Atslēgas vārdi allyl amine, Lewis acids, oxazoline, trichloroacetimidate, cyclization
Anotācija A novel efficient and eco-friendly method for the synthesis of 2-trichloromethyl-4-vinyloxazoline is presented that involves Lewis acid-catalyzed cyclization of bisimidate derived from but-3-ene-1,2-diol. The derivatization potential of 2-trichloromethyl-4-vinyloxazoline is demonstrated by ring opening reactions with water, hydrobromic acid, hydrochloric acid, and acetic acid leading to allylamine derivatives.
DOI: 10.1007/s10593-012-1077-0
Hipersaite: http://link.springer.com/article/10.1007%2Fs10593-012-1077-0# 
Atsauce Grigorjeva, L., Maļeckis, A., Kļimoviča, K., Skvorcova, M., Ivdra, N., Leitis, G., Jirgensons, A. Novel Synthesis of 2-Trichloromethyl-4-Vinyloxazoline and Its Derivatization by Ring Cleavage Reactions. Chemistry of Heterocyclic Compounds, 2012, Vol.48, Iss.6, 919.-924.lpp. e-ISSN 1573-8353. ISSN 0009-3122. Pieejams: doi:10.1007/s10593-012-1077-0
Papildinformācija Citējamību skaits:
ID 13842