Iodonium Salts Are Key Intermediates in Pd-Catalyzed Acetoxylation of Pyrroles

ChemInform 2011
Dmitrijs Lubriks, D. Sokolovs, Edgars Sūna

The reaction of pyrroles and indoles with Ph-I(O-Ac)2 proceeds via initial regioselective formation of iodonium acetate intermediates which are converted into acetoxy derivatives.

Atslēgas vārdi
pyrrole derivatives; oxidation, dehydrogenation; halogenation; indole derivatives, isoindole derivatives
DOI
10.1002/chin.201152100
Hipersaite
http://dx.doi.org/10.1002/chin.201152100

Lubriks, D., Sokolovs, D., Sūna, E. Iodonium Salts Are Key Intermediates in Pd-Catalyzed Acetoxylation of Pyrroles. ChemInform, 2011, Vol.42, Iss.52, 100.-100.lpp. ISSN 1522-2667. Pieejams: doi:10.1002/chin.201152100

Publikācijas valoda
English (en)