Reclamation of Post-Consumer Plastics for Development of Polycarbonate and Acrylonitrile Butadiene Styrene Based Nanocomposites with Nanoclay
AIP Conference Proceedings 2016
Jānis Zicāns, Remo Merijs-Meri, Tatjana Ivanova, Rita Bērziņa, Ruta Saldābola, Roberts Maksimovs

Suitability of recycled acrylonitrile-butadiene-styrene (R-ABS) and recycled polycarbonate (R-PC) for the development of polymer matrix nanocomposites with organically modified nanoclay (OMMT) is evaluated in comparison to virgin polymers (V-ABS and V-PC) based systems. The influence of OMMT content on the structure as well as calorimetric, mechanical and thermal properties of virgin and recycled polymers containing systems is revealed. Increase in stiffness and strength of virgin and recycled polymers based systems is observed along with rising nanoclay content. However, it is observed that reinforcing efficiency of clays on the R-ABS containing systems is reduced to certain extent in comparison to those, based on virgin polymers. It is shown, that in the presence of OMMT approximation of glass transition temperatures of both polymeric components is observed, which can testify about certain improvement of compatibility between PC and ABS. Increment of the modulus of elasticity and yield strength of the nanocomposites is associated with anisodiametric shape of OMMT, as well as with intercalation of polymer within the interlaminar space of the clay nanoparticles. It is also demonstrated that addition of nanoclay improves thermogravimetric behavior of the investigated compositions. Consequently, it is suggested that nanoclays can be used as promising functional additives and replace halogenated flame-retardants, without reducing mechanical properties of the composites.


Atslēgas vārdi
Nanocomposites, Reinforced polymers, Elastic moduli, Glass transitions, Nanoparticles
DOI
10.1063/1.4949728
Hipersaite
http://scitation.aip.org/content/aip/proceeding/aipcp/10.1063/1.4949728

Zicāns, J., Merijs-Meri, R., Ivanova, T., Bērziņa, R., Saldābola, R., Maksimovs, R. Reclamation of Post-Consumer Plastics for Development of Polycarbonate and Acrylonitrile Butadiene Styrene Based Nanocomposites with Nanoclay. No: AIP Conference Proceedings, Itālija, Naples, 19.-23. jūnijs, 2016. Melville: American Institute of Physics, 2016, 020153.-020153.lpp. ISBN 978-0-7354-1287-3. ISSN 0094-243X. e-ISSN 1551-7616. Pieejams: doi:10.1063/1.4949728

Publikācijas valoda
English (en)
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