Synthesis and Applications of Silyl 2-Methylprop-2-ene-1-sulfinates in Preparative Silylation and GC-Derivatization Reactions of Polyols and Carbohydrates

ChemInform 2016
Dean Markovic, Wandji Augustin Tchawou, Irina Novosjolova, Sylvain Laclef, Dmitrijs Stepanovs, Māris Turks, Pierre Vogel

Trimethylsilyl, triethylsilyl, tert-butyldimethylsilyl, and triisopropylsilyl 2-methylprop-2-ene-1-sulfinates are prepared by Cu-catalyzed sila-ene reactions of methallylsilanes with SO2.

Atslēgas vārdi
silyl 2-methylprop-2-ene-1-sulfinates, Cu-catalyzed sila-ene reaction, methallylsilanes, SO2.
DOI
10.1002/chin.201631209

Markovic, D., Tchawou, W., Novosjolova, I., Laclef, S., Stepanovs, D., Turks, M., Vogel, P. Synthesis and Applications of Silyl 2-Methylprop-2-ene-1-sulfinates in Preparative Silylation and GC-Derivatization Reactions of Polyols and Carbohydrates. ChemInform, 2016, Vol.47, Iss.31, 1.-1.lpp. e-ISSN 1522-2667. Pieejams: doi:10.1002/chin.201631209

Publikācijas valoda
English (en)