Carbenium Ion Formation by Fragmentation of Electrochemically Generated Oxonium Ions

Organic and Biomolecular Chemistry 2018
Anna Lielpētere, Aigars Jirgensons

Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at a low oxidation potential in the presence of a nucleophile. The application of this concept is demonstrated for the allylation of carbenium ions generated by the anodic oxidation of stannylmethylethers.

DOI
10.1039/c8ob01339j
Hipersaite
https://pubs.rsc.org/en/content/articlelanding/2018/ob/c8ob01339j#!divAbstract

Lielpētere, A., Jirgensons, A. Carbenium Ion Formation by Fragmentation of Electrochemically Generated Oxonium Ions. Organic and Biomolecular Chemistry, 2018, Vol.16, Iss.28, 5094.-5096.lpp. ISSN 1477-0520. Pieejams: doi:10.1039/c8ob01339j

Publikācijas valoda
English (en)